Cross-laminated timber has been used in buildings since the 1990s. In the last years, there has been a growing interest in the use of this technology, especially with the adoption of the product in increasingly taller buildings. Considering that the product is manufactured from a combustible material, wood, authorities that regulate the fire safety in buildings and the scientific community have carried out numerous research and fire tests, aiming to elaborate codes which contemplate the use of cross-laminated timber in tall buildings. This paper discusses the main results obtained from the fire resistance test of a cross-laminated timber slab carried out in the horizontal gas furnace (3.0 m × 4.0 m x 1.5 m) from the University of Sao Paulo. A vertical load of 3 kN/m2 was applied over the slab and the specimens were exposed to the standard fire curve for 30 min. In addition to the 30-min test, the research also evaluated the thermal behavior of the samples during the 24 h after the burners were turned off. Throughout the test, the slab maintained the integrity and the thermal insulation, and no falling-off of the charred layer was observed. However, the 24-h test indicated that it is mandatory to consider the loss of stiffness and strength of timber caused by the thermal wave observed during the decay phase.