Connections in mass timber structural systems dissipate energy and transfer lateral forces from mass timber elements such as shear walls and diaphragms, providing critical load paths. Cross-laminated timber (CLT) is a prominent mass timber material used to manufacture wall and floor assemblies. Fire performance research of CLT walls and floors has been abundant in recent years in an effort to address concerns about fires in tall wood buildings. Some fire-protected structural elements, including connections, may not be directly exposed to flames in a fire event but will experience elevated temperatures. There is limited research on elevated temperature performance of CLT connections, and consequentially a lack of full understanding of the fire performance of CLT structures. Therefore, a series of cyclic shear tests were conducted on a CLT wall-to-floor bracket connection assembly to characterize thermal degradation according to a matrix of 28 exposure duration-temperature combinations. The first study developed simple models to predict thermal degradation of two basic engineering parameters, peak strength and elastic stiffness. The second study used two different methods to develop force-displacement backbone models from the experimental hysteresis data. Results from both studies indicate significant thermal degradation of the connection performance at elevated temperatures ranging between 75 °C to 200 °C. This research is a step towards holistic evaluation of elevated temperature modeling of CLT structures.